PG54897.B00490
(354.) Cold has been considered by some as a positive quality, the effect of a cause antagonist to that of heat; but this idea seems now (with perhaps a single exception) to be universally abandoned. The sensation of cold is as easily explicable by the passage of heat outwards through the surface of the body as that of heat by its ingress from without; and the experiments cited in proof of a radiation of cold are all perfectly explained by Prevost’s theory of reciprocal interchange. It is remarkable, however, how very limited our means of producing intense cold are, compared with those we possess of effecting the accumulation of heat in bodies. This is one of the strongest arguments adducible in favour of the doctrines of those who maintain the possibility of exhausting the heat of a body altogether, and leaving it in a state absolutely devoid of it. But we ought to consider, that the known methods of generating heat chiefly turn on the production of chemical combinations: we may easily conceive, therefore, that, to obtain equally powerful corresponding frigorific effects, we ought to possess the means of effecting a disunion equally extensive and rapid between such elements, actually combined, as have already produced heat by their union. This, however, we can only accomplish by engaging them in combinations still more energetic, that is to say, in which we may reasonably expect more heat to be produced by the new combination than would be destroyed or abstracted by the proposed decomposition. Chemistry, however, (unaided by electric agency,) affords no means of suddenly breaking the union of two elements, and presenting _both_ in an uncombined state. A certain analogy to such disunion, however, and its consequences, may be traced in the sudden expansion of condensed gases from a liquid state into vapour, which is the most powerful source of cold known.

PG54897.B00491
(355.) The dilatation of bodies by heat forms the subject of that branch of science called pyrometry. There is no body but is capable of being penetrated by heat, though some with greater, others with less rapidity; and being so penetrated, all bodies (with a very few exceptions, and those depending on very peculiar circumstances,) are dilated by it in bulk, though with a great diversity in the amount of dilatation produced by the same degree of heat. Of the several forms of natural bodies, gases and vapours are observed to be most dilatable; liquids next, and solids least of all. The dilatation of solids has been made a subject of repeated and careful measurement by several experimenters; among whom, Smeaton, Lavoisier, and Laplace, are the principal. The remarkable discovery of the unequal dilatation of crystallised bodies by Mitscherlich has already been spoken of. (266.) That of gases and vapours was examined about the same time by Dalton and Gay-Lussac, who both arrived independently at the conclusion of an equal dilatability subsisting in them all, which constitutes one of the most remarkable points in their history.

PG54897.B00492
(356.) The dilatation of air by heat affords, perhaps, the most unexceptionable means known of measuring degrees of heat. The thermometer, as originally constructed by Cornelius Drebell, was an air thermometer. Those now in common use measure accessions of heat not by the degree of dilatation of air but of mercury. It has been shown, by the researches of Dulong and Petit, that its indications coincide exactly with that of the air-thermometer in moderate temperatures; though at very elevated ones they exhibit a sensible, and even considerable, deviation. By this instrument, which owes its present convenience and utility to the happy idea of Newton, who first thought of fixing determinate points on its scale, we are enabled to estimate, or at least identify, the degrees of heat; and thereby to investigate with accuracy the laws of its communication and its other properties. Were we sure that equal additions of heat produced equal increments of dimension in any substance, the indications of a thermometer would afford a true and secure _measure_ of the quantity present; but this is so far from being the case, that we are nearly in total ignorance on this important point; a circumstance which throws the greatest difficulty in the way of all theoretical reasoning, and even of experimental enquiry. The laws of the dilatation of liquids, in consequence of this deficiency of necessary preliminary knowledge, are still involved in great obscurity, notwithstanding the pains which have been bestowed on them by the elaborate experiments and calculations of Gilpin, Blagden, Deluc, Dalton, Gay-Lussac, and Biot.

PG54897.B00493
(357.) The most striking and important of the effects of heat consist, however, in the liquefaction of solid substances, and the conversion of the liquids so produced into vapour. There is no solid substance known which, by a sufficiently intense heat, may not be melted, and finally dissipated in vapour; and this analogy is so extensive and cogent, that we cannot but suppose that all those bodies which are liquid under ordinary circumstances, owe their liquidity to heat, and would freeze or become solid if their heat could be sufficiently reduced. In many we see this to be the case in ordinary winters; for some, severe frosts are requisite; others freeze only with the most intense artificial colds; and some have hitherto resisted all our endeavours; yet the number of these last is few, and they will probably cease to be exceptions as our means of producing cold become enlarged.

PG54897.B00494
(358.) A similar analogy leads us to conclude that all aëriform fluids are merely liquids kept in the state of vapour by heat. Many of them have been actually condensed into the liquid state by cold accompanied with violent pressure; and as our means of applying these causes of condensation have improved, more and more refractory ones have successively yielded. Hence we are fairly entitled to extend our conclusion to those which we have not yet been able to succeed with; and thus we are led to regard it as a general fact, that the liquid and aëriform or vaporous states are entirely dependent on _heat_; that were it not for this cause, there would be nothing but solids in nature; and that, on the other hand, nothing but a sufficient intensity of heat is requisite to destroy the cohesion of every substance, and reduce all bodies, first to liquids, and then into vapour.

PG54897.B00495
(359.) But solids, themselves, by the abstraction of heat shrink in dimension, and at the same time become harder, and more brittle; yielding less to pressure, and permitting less separation between their parts by tension. These facts, coupled with the greater compressibility of liquids, and the still greater of gases, strongly induce us to believe that it is heat, and heat alone, which holds the particles of all bodies at that distance from each other which is necessary to allow of compression; which in fact gives them their elasticity, and acts as the antagonist force to their mutual attraction, which would otherwise draw them into actual contact, and retain them in a state of absolute immobility and impenetrability. Thus we learn to regard heat as one of the great maintaining powers of the universe, and to attach to all its laws and relations a degree of importance which may justly entitle them to the most assiduous enquiry.

PG54897.B00496
(360.) It was first ascertained by Dr. Black that when heat produces the liquefaction of a solid, or the conversion of a liquid into vapour, the liquid or the vapour resulting is no _hotter_ than the solid or liquid from which it was produced, though a great deal of heat has been expended in producing this effect, and has actually entered into the substance.

PG54897.B00497
(361.) Hence he drew the conclusion that it has become _latent_, and continues to exist in the product, maintaining it in its new state, without increasing its temperature. He further proved, that when the vapour condenses, or the liquid freezes, this latent heat is again given out from it. This great discovery, with its natural and hardly less important concomitant, that of the difference of specific heats in different bodies, or the different quantities of heat they require to raise their temperature equally, are the chief reasons for regarding heat as a material substance in a more decided manner than light, with which in its radiant state it holds so close an analogy.

PG54897.B00498
(362.) The subject of latent heat has been far less attentively studied than its great practical importance would appear to demand, when we consider that it is to this part of physical science that the theory of the steam-engine is mainly referable, and that material improvements may not unreasonably be expected in that wonderful instrument, from a more extended knowledge than we possess of the latent heats of different vapours. This is not the case, however, with the subject of specific heat, which was followed up immediately after its first promulgation with diligence by Irvine; and, after a brief interval, by Lavoisier and Laplace, as well as by our countryman Crawfurd, who determined the specific heats of many substances, both solid and liquid. After a considerable period of inactivity, the subject was again resumed by Delaroche and Berard, and subsequently by Dulong and Petit: the result of whose investigations has been the inductive establishment of one of those simple and elegant physical laws which carry with them, if not their own evidence, at least their own recommendation to our belief, as being in unison with every thing we know of the harmony of nature. The law to which we allude is this:--that the atoms of all the simple chemical elements have exactly the same capacity for heat, or are all equally heated or cooled by equal accessions or abstractions of heat. It is only among laws like this that we can expect to find a clew capable of guiding us to a knowledge of the true nature of heat, and its relations to ponderable matter.

PG54897.B00499
_Magnetism and Electricity._

PG54897.B00500
(363.) These two subjects, which had long maintained a distinct existence, and been studied as separate branches of science, are at length effectually blended. This is, perhaps, the most satisfactory result which the experimental sciences have ever yet attained. All the phenomena of magnetic polarity, attraction, and repulsion, have at length been resolved into one general fact, that two currents of electricity, moving in the same direction repel, and in contrary directions attract, each other. The phenomena of the communication of magnetism and what is called its induced state, alone remain unaccounted for; but the interesting theory which has been developed by M. Ampere, under the name of Electro-dynamics, holds out a hope that this difficulty will also in its turn give way, and the whole subject be at length completely merged, as far as the consideration of the acting causes goes, in the more general one of electricity. This, however, does not prevent magnetism from maintaining its separate importance as a department of physical enquiry, having its own peculiar laws and relations of the highest practical interest, which are capable of being studied quite apart from all consideration of its electrical origin. And not only so, but to study them with advantage, we must proceed as if that origin were totally unknown, and, at least up to a certain point, and that a considerably advanced one, conduct our enquiries into the subject on the same inductive principles as if this branch of physics were absolutely independent of all others.

PG54897.B00501
(364.) Iron, and its oxides and alloys, were for a long time the only substances considered susceptible of magnetism. The loadstone was even one of the examples produced by Bacon of that class of physical instances to which he applies the term “Instantiæ monodicæ”--_singular instances_. And the history of magnetism affords a beautiful comment on his remark on instances of this sort. “Nor should our enquiries,” he observes, “into their nature be broken off, till the properties and qualities found in such things as may be esteemed wonders in nature are reduced and comprehended under some certain law; so that all irregularity or singularity may be found to depend upon some common form, and the wonder only rest in the exact differences, degrees, or extraordinary concurrence, and not in the species itself.” The discovery of the magnetism of nickel, which though inferior to that of iron, is still considerable; that of cobalt, yet feebler, and that of titanium, which is only barely perceptible, have effectually broken down the imaginary limit between iron and the other materials of the world, and established the existence of that general law of continuity which it is one chief business of philosophy to trace throughout nature. The more recent discoveries of M. Arago (mentioned in 160.) have completed this generalization, by showing that there is no substance but which, under proper circumstances, is capable of exhibiting unequivocal signs of the magnetic virtue. And to obliterate all traces of that line of separation which was once so broad, we are now enabled, by the great discovery of Oërsted, to communicate at and during pleasure to a coiled wire of any metal indifferently all the properties of a magnet;--its attraction, repulsion, and polarity; and _that_ even in a more intense degree than was previously thought to be possible in the best natural magnets. In short, in this case, and in this case only, perhaps, in science, have we arrived at that point which Bacon seems to have understood by the discovery of “forms.” “The _form_ of any nature,” says he, “is such, that where it is, the given nature must infallibly be. The form, therefore, is perpetually present when that nature is present; ascertains it universally, and accompanies it every where. Again, this form is such, that when removed, the given nature infallibly vanishes. Lastly, a true form is such as can deduce a given nature from some essential property, which resides in many things.”

PG54897.B00502
(365.) Magnetism is remarkable in another important point of view. It offers a prominent, or “_glaring instance_” of that quality in nature which is termed _polarity_ (267.), and that under circumstances which peculiarly adapt it for the study of this quality. It does not appear that the ancients had any knowledge of this property of the magnet, though its attraction of iron was well known to them. The first mention of it in modern times cannot be traced earlier than 1180, though it was probably known to the Chinese before that time. The polarity of the magnet consists in this, that if suspended freely, one part of it will invariably direct itself towards a certain point in the horizon, the other towards the opposite point; and that, if two magnets, so suspended, be brought near each other, there will take place a mutual action, in consequence of which, the positions of both will be disturbed, in the same manner as would happen if the corresponding parts of each repelled, and those oppositely directed attracted, each other; and by properly varying the experiment, it is found that they really do so. If a small magnet, freely suspended, be brought into the neighbourhood of a larger one, it will take a position depending on the position of the _poles_ of the larger one, with respect to its point of suspension. And it has been ascertained that these and all other phenomena exhibited by magnets in their mutual attractions and repulsions are explicable on the supposition of two forces or virtues lodged in the particles of the magnets, the one predominating at one end, the other at the other; and such that each particle shall attract those in which the _opposite_ virtue to its own prevails, and repel those in which a _similar_ one resides with a force proportional to the inverse square of their mutual distance.

PG54897.B00503
(366.) The direction in which a magnetic bar, or needle of steel, freely suspended, places itself, has been ascertained to be different at different points of the earth’s surface. In some places it points exactly north and south, in others it deviates from this direction more or less, and at some actually stands at right angles to it. This remarkable phenomenon, which is called the variation of the needle, and which was discovered by Sebastian Cabot in the year 1500, is accompanied with another called the dip, noticed by Robert Norman in 1576. It consists in a tendency of a needle, nicely balanced on its centre, when unmagnetized, to _dip_ or point downwards when rendered magnetic, towards a point below the horizon, and situated within the earth. By tracing the variation and dip over the whole surface of the globe, it has been found that these phenomena take place as they would do if the earth itself were a great magnet, having its poles deeply situated below the surface,--and, what is very remarkable, possessing a slow motion within it, in consequence of which neither the variation nor dip remain constantly the same at the same place. The laws of this motion are at present unknown; but the discovery of electro-magnetism, by rendering it almost certain that the earth’s magnetism is merely an effect of the continual circulation of great quantities of electricity round it, in a direction generally corresponding with that of its rotation, have dissipated the greater part of the mystery which hung over these phenomena; since a variety of causes, both geological and others, may be imagined which may produce considerable deviations in the intensity, and partial ones in the direction, of such electric currents. The unequal distribution of land and sea in the two hemispheres, by affecting the operation of the sun’s heat in producing evaporation from the latter, which is probably one of the great sources of terrestrial electricity, may easily be conceived to modify the general tendency of such currents, and to produce irregularities in them, which may render a satisfactory account of whatever still appears anomalous in the phenomena of terrestrial magnetism. This branch of science thus becomes connected, on a great scale, with that of meteorology, one of the most complicated and difficult, but at the same time interesting, subjects of physical research; one, however, which has of late begun to be studied with a diligence which promises the speedy disclosure of relations and laws of which at present we can form but a very imperfect notion.

PG54897.B00504
(367.) The communication of magnetism from the earth to a magnetic body, or from one magnetic body to another, is performed by a process to which the name of induction has been given, and the laws and properties of such induced magnetism have been studied with much perseverance and success,--practically, by Gilbert, Boyle, Knight, Whiston, Cavallo, Canton, Duhamel, Rittenhouse, Scoresby, and others; and theoretically, by Æpinus, Coulomb, and Poisson, and in our own country by Messrs. Barlow and Christie, who have investigated with great care the curious phenomena which take place when masses of iron are presented successively, in different positions, by rotation on an axis, to the influence of the earth’s magnetism. The magnetism of crystallized bodies (partly from the extreme rarity of such as are susceptible of any considerable magnetic virtue) has not hitherto been at all examined, but would probably afford very curious results.

PG54897.B00505
(368.) To electricity the views of the physical enquirer now turn from almost every quarter, as to one of those universal powers which Nature seems to employ in her most important and secret operations. This wonderful agent, which we see in intense activity in lightning, and in a feebler and more diffused form traversing the upper regions of the atmosphere in the northern lights, is present, probably in immense abundance, in every form of matter which surrounds us, but becomes sensible only when disturbed by excitements of peculiar kinds. The most effectual of these is friction, which we have already observed to be a powerful source of heat. Everybody is familiar with the crackling sparks which fly from a cat’s back when stroked. These, by proper management, may be accumulated in bodies suitably disposed to receive them, and, although then no longer visible, give evidence of their existence by the exhibition of a vast variety of extraordinary phenomena,--producing attractions and repulsions in bodies at a distance,--admitting of being transferred by contact, or by sudden and violent transilience of the interval of separation, from one body to another, under the form of sparks and flashes;--traversing with perfect facility the substance of the densest metals, and a variety of other bodies called conductors, but being detained by others, such as glass, and especially _air_, which are thence called non-conductors,--producing painful shocks and convulsive motions, and even death itself if in sufficient quantity, in animals through which they pass, and finally imitating, on a small scale, all the effects of lightning.

PG54897.B00506
(369.) The study of these phenomena and their laws until a comparatively recent period occupied the entire attention of electricians, and constituted the whole of the science of electricity. It appears, as the result of their enquiries, that all the phenomena in question are explicable on the supposition that electricity consists in a rare, subtle, and highly elastic fluid, which in its tendency to expand and diffuse itself pervades with more or less facility the substance of conductors, but is obstructed and detained from expansion more or less completely by non-conductors. It is supposed, moreover, that this electric fluid possesses a power of attraction for the particles of all ponderable matter, together with that of a repulsion for particles of its own kind. Whether it has weight, or is rather to be regarded as a species of matter distinct from that of which ponderable bodies consist, is a question of such delicacy, that no direct experiments have yet enabled us to decide it; but at all events its _inertia_ compared with its elastic force must be conceived excessively small, so that it is to be regarded as a fluid in the highest degree _active_, obeying every impulse, internal or external, with the greatest promptitude; in short, a fluid whose energies can only be compared with those of the ethereal medium by which, in the undulatory doctrine, light is supposed to be conveyed. The properties of hydrogen gas compared with those of the denser aëriform fluids will, in some slight degree, aid our conception of the excessive mobility and penetrating activity of a fluid so constituted. Electricity, however, must be regarded as differing in some remarkable points from all those fluids to which we have hitherto been accustomed to apply the epithet elastic, such as air, gases, and vapours. In these, the repulsive force of the particles on which their elasticity depends is considered as extending only to very small distances, so as to affect only those in the immediate vicinity of each other, while their attractive power, by which they obey the general gravitation of all matter, extends to any distance. In electricity, on the other hand, the very reverse must be admitted. The force by which its particles repel each other extends to great distances, while its force of adhesion to ponderable matter must be regarded as limited in its extent to such minute intervals as escape observation.

PG54897.B00507
(370.) The conception of a single fluid of this kind, which when accumulated in excess in bodies tends constantly to escape, and seek a restoration of equilibrium by communicating itself to any others where there may be a deficiency, is that which occurs most naturally to the mind, and was accordingly maintained by Franklin, to whom the science of electricity is under great obligations for those decisive experiments which informed us respecting the true nature of lightning. The same theory was afterwards advocated by Æpinus, who first showed how the laws of equilibrium of such a fluid might be reduced to strict mathematical investigation. But there are phenomena accompanying its transfer from body to body and the state of equilibrium it affects under various circumstances, which appear to require the admission of _two distinct fluids_ antagonist to each other, each attracting the other, and repelling itself; but each, alike, susceptible of adhesion to material substances, and of transfer more or less rapid from particle to particle of them. These fluids in the natural undisturbed state are conceived to exist in a state of combination and mutual saturation; but this combination may be broken, and either of them separately accumulated in a body to any amount without the other, provided its escape be properly obstructed by surrounding it with non-conductors. When so accumulated, its repulsion for its own kind and attraction of the opposite species in neighbouring bodies tends to disturb the natural equilibrium of the two fluids present in them, and to produce phenomena of a peculiar description, which are termed _induced_ electricity. Curious and artificial as this theory may appear, there has hitherto been produced no phenomenon of which it will not afford at least a plausible, and in by far the majority of cases a very satisfactory, explanation. It has one character which is extremely valuable in any theory, that of admitting the application of strict mathematical reasoning to the conclusions we would draw from it. Without this, indeed, it is scarcely possible that any theory should ever be fairly brought to the test by a comparison with facts. Accordingly, the mathematical theory of electrical equilibrium, and the laws of the distribution of the electric fluids over the surfaces of bodies in which they are accumulated, have been made the subject of elaborate geometrical investigation by the most expert mathematicians, and have attained a degree of extent and elegance which places this branch of science in a very high rank in the scale of mathematico-physical enquiry. These researches are grounded on the assumption of a law of attraction and repulsion similar to those of gravity and magnetism, and which by the general accordance of the results with facts, as well as by experiments instituted for the express purpose of ascertaining the laws in question, are regarded as sufficiently demonstrated.
